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Cleaning products giant Ecolab Inc. (ECL) confirmed plans to buy Nalco Holding Co. (NLC), which makes chemicals used in water treatment, pollution control and energy conservation, for $5.38 billion.

The Wall Street Journal reported late Tuesday that a deal was in the works.

Nalco holders will have the option to receive 0.7005 shares of Ecolab or $38.80 a share in cash, a 34% premium to Tuesday's close.

Nalco shares surged 32% to $38.25 premarket, while Ecolab was inactive and closed Tuesday at $55.39.

Including debt assumption, the deal, which is expected to add to earnings beginning next year, is worth $8.1 billion.

Naperville, Ill.-based Nalco is one of the world's largest producers of chemicals aimed at reducing resource consumption and minimizing environmental releases, according to the company's website.

Founded in 1928 as National Aluminate Corp., Nalco was publicly traded until 1999, when French utilities giant GDF Suez SA [then known as Suez Lyonnaise des Eaux] bought it for $4.1 billion. In 2003, Suez sold it to a group composed of Blackstone Group, Apollo Management and Goldman Sachs Capital Partners for $4.2 billion. The company filed to go public a year later.

Ecolab, headquartered in St. Paul, Minn., provides cleaning, sanitizing and infection-control services to customers in the food service, hospitality, healthcare and other industries. The company took in more than $6 billion in 2010 annual revenue and employs roughly 26,500 people.

Ecolab also has a water, energy and waste division that includes services for waste water management, process filtration and cooling water treatment.

Ecolab has been steadily acquiring smaller assets in recent years. In the last year, Ecolab acquired the assets of privately held O.R. Solutions Inc., a Virginia-based company that develops and markets surgical fluid warming and cooling systems for about $260 million.

Last September, Ecolab also acquired the assets of the Cleantec business of Australia's Campbell Brothers Ltd., which develops and markets cleaning and hygiene products mainly for the Australian food and beverage processing, food service, hospitality and textile care markets. Terms of the deal weren't publicized.

Also last September, the commercial laundry division of Dober Chemical Corp., a privately held Illinois firm, was also sold to Ecolab. Details of that transaction also weren't disclosed.

The industrials sector has seen a handful of large deals in recent months, including Sealed Air Corp.'s nearly $3 billion purchase of Ecolab's smaller rival Diversey Holdings, which makes commercial cleaning, food sanitation and hygiene products.

Ecolab also said it expects adjusted earnings for second quarter of 64 cents a share, the top end of its prior range, and raised its estimate for the year before considering the deal to $2.52 to $2.56, from its prior outlook of $2.49 to $2.53.

Meanwhile, Nalco projected earnings of 47 cents a share on sales of $1.2 billion, while analysts polled by Thomson Reuters were looking for 36 cents and $1.12 billion.

-By Gina Chon and Anupreeta Das, The Wall Street Journal

--Lauren Pollock contributed to this article

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