By Dana Mattioli And Gillian Tan 

Private-equity firm Sycamore Partners is in advanced talks to buy women's apparel retailer Chico's FAS Inc., according to people familiar with the matter, in what could be the largest leveraged buyout so far this year.

New York-based Sycamore was recently seeking financing for a buyout of Chico's, indicating a deal could be close, according to one of the people. There is no guarantee there will be a deal, however, or that another firm won't ultimately buy Chico's instead. Another deal Sycamore was recently negotiating fell apart because the buyout firm had trouble lining up funding on acceptable terms.

Chico's had a market capitalization of $2.65 billion at Tuesday's close, meaning that with a typical takeover premium, the company could be valued at more than $3 billion. There hasn't been an LBO even close to that size so far this year, according to Dealogic.

Sizable leveraged buyouts--especially of public companies like Chico's--have been few and far between in recent years. Even though cheap financing has been plentiful, the rising stock market in many cases has put company valuations out of the reach of private-equity firms. Last year, there were just $23 billion in private-equity buyouts of public companies in the U.S., according to Dealogic.

Still, there have been exceptions. In December, a consortium led by BC Partners agreed to buy another public retailer, PetSmart Inc. for about $8.2 billion.

Chico's shares fell slightly in regular trading Tuesday, to $17.25. They have risen just 1% in the past year despite long-running speculation that the company would be sold.

In addition to its namesake stores, which tend to cater to older women, Chico's has other brands including White House Black Market, lingerie label Soma, and online and catalog retailer Boston Proper. Across its brands, the Fort Myers, Fla., company has more than 1,550 stores throughout the U.S. and Canada, according to its website.

In the quarter ending Nov. 1, Chico's reported sales of $665.6 million and earnings of $26.5 million.

Sycamore has been active in the retail sector of late. Last year, it took Jones Group private in a $1.2 billion deal, and last month it agreed to sell shoe company Stuart Weitzman to Coach Inc.

But in January, Express Inc., a retailer that focuses on young adults, said it ended buyout talks with Sycamore after several months, citing the private-equity firm's inability to find acceptable financing for a deal.

Write to Dana Mattioli at dana.mattioli@wsj.com and Gillian Tan at gillian.tan@wsj.com

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