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                                 UNITED STATES
                       SECURITIES AND EXCHANGE COMMISSION
                             Washington, D.C. 20549

                                   FORM N-Q

                   QUARTERLY SCHEDULE OF PORTFOLIO HOLDINGS
    OF REGISTERED MANAGEMENT INVESTMENT COMPANY



  Investment Company Act file number 811-01835


                      Pioneer Value Fund
               (Exact name of registrant as specified in charter)


                       60 State Street, Boston, MA 02109
              (Address of principal executive offices) (ZIP code)


            Dorothy E. Bourassa, Pioneer Investment Management, Inc.,
                       60 State Street, Boston, MA 02109
                    (Name and address of agent for service)


Registrant's telephone number, including area code:  (617) 742-7825


Date of fiscal year end:  September 30

Date of reporting period:  January 31, 2013

Form N-Q is to be used by management investment companies, other than small
business investment companies registered on Form N-5 (239.24 and 274.5 of this
chapter), to file reports with the Commission, not later than 60 days after
close of the first and third fiscal quarters, pursuant to Rule 30b1-5 under
the Investment Company Act of 1940 (17 CFR 270.30b1-5).  The Commission may
use the information provided on Form N-Q in its regulatory, disclosure review,
inspection, and policymaking roles.

A registrant is required to disclose the information specified by Form N-Q,
and the Commission will make this information public. A registrant is not
required to respond to the collection of information contained in Form N-Q
unless the Form displays a currently valid Office of Management and Budget
("OMB") control number. Please direct comments concerning the accuracy of the
information collection burden estimate and any suggestions for reducing the
burden to Secretary, Securities and Exchange Commission, 450 Fifth Street, NW,
Washington, DC 20549-0609.  The OMB has reviewed this collection of information
under the clearance requirements of 44 U.S.C. ss. 3507.


<PAGE>
ITEM 1. Schedule of Investments.






       
Pioneer Value Fund
   
       
Schedule of Investments 12/31/12
   
             
 
Shares
       
Value
       
COMMON STOCKS - 99.9%
   
       
Energy - 15.5%
   
       
Oil & Gas Equipment & Services - 4.0%
   
 
678,300
   
Halliburton Co.
$
23,530,227
 
408,300
   
Schlumberger, Ltd.
 
28,291,107
         
$
51,821,334
       
Integrated Oil & Gas - 7.4%
   
 
550,200
   
Chevron Corp.
$
59,498,628
 
476,600
   
Occidental Petroleum Corp.
 
36,512,326
         
$
96,010,954
       
Oil & Gas Exploration & Production - 4.1%
   
 
1,743,700
   
Marathon Oil Corp.
$
53,461,842
       
Total Energy
$
201,294,130
       
Materials - 2.1%
   
       
Diversified Metals & Mining - 2.1%
   
 
797,400
   
Freeport-McMoRan Copper & Gold, Inc.
$
27,271,080
       
Total Materials
$
27,271,080
       
Capital Goods - 7.9%
   
       
Aerospace & Defense - 4.5%
   
 
477,400
   
Honeywell International, Inc.
$
30,300,578
 
342,700
   
United Technologies Corp.
 
28,104,827
         
$
58,405,405
       
Industrial Conglomerates - 3.4%
   
 
2,120,800
   
General Electric Co.
$
44,515,592
       
Total Capital Goods
$
102,920,997
       
Transportation - 1.0%
   
       
Railroads - 1.0%
   
 
672,500
   
CSX Corp.
$
13,268,425
       
Total Transportation
$
13,268,425
       
Media - 6.9%
   
       
Cable & Satellite - 2.1%
   
 
714,800
   
Comcast Corp.
$
26,719,224
       
Movies & Entertainment - 4.8%
   
 
1,193,200
   
News Corp.
$
30,474,328
 
649,800
   
The Walt Disney Co.
 
32,353,542
         
$
62,827,870
       
Total Media
$
89,547,094
       
Retailing - 1.5%
   
       
Department Stores - 1.5%
   
 
504,800
   
Macy's, Inc.
$
19,697,296
       
Total Retailing
$
19,697,296
       
Food & Staples Retailing - 3.4%
   
       
Drug Retail - 1.3%
   
 
352,700
   
CVS Caremark Corp.
$
17,053,045
       
Hypermarkets & Super Centers - 2.1%
   
 
401,900
   
Wal-Mart Stores, Inc.
$
27,421,637
       
Total Food & Staples Retailing
$
44,474,682
       
Food, Beverage & Tobacco - 4.3%
   
       
Soft Drinks - 1.1%
   
 
432,800
   
Coca-Cola Enterprises, Inc.
$
13,732,744
       
Tobacco - 3.2%
   
 
659,200
   
Altria Group, Inc.
$
20,712,064
 
248,800
   
Philip Morris International, Inc.
 
20,809,632
         
$
41,521,696
       
Total Food, Beverage & Tobacco
$
55,254,440
       
Health Care Equipment & Services - 5.2%
   
       
Health Care Equipment - 2.4%
   
 
535,700
   
Covidien Plc
$
30,931,318
       
Managed Health Care - 2.8%
   
 
679,700
   
UnitedHealth Group, Inc.
$
36,866,928
       
Total Health Care Equipment & Services
$
67,798,246
       
Pharmaceuticals, Biotechnology & Life Sciences - 15.0%
 
       
Biotechnology - 2.5%
   
 
368,400
   
Amgen, Inc.
$
31,800,288
       
Pharmaceuticals - 12.5%
   
 
673,600
   
Johnson & Johnson
$
47,219,360
 
1,181,200
   
Merck & Co., Inc.
 
48,358,328
 
2,679,500
   
Pfizer, Inc.
 
67,201,860
         
$
162,779,548
       
Total Pharmaceuticals, Biotechnology & Life Sciences
$
194,579,836
       
Banks - 6.8%
   
       
Diversified Banks - 3.1%
   
 
1,181,700
   
Wells Fargo & Co.
$
40,390,506
       
Regional Banks - 3.7%
   
 
457,500
   
BB&T Corp.
$
13,317,825
 
581,800
   
PNC Financial Services Group, Inc.
 
33,924,758
         
$
47,242,583
       
Total Banks
$
87,633,089
       
Diversified Financials - 11.8%
   
       
Other Diversified Financial Services - 5.2%
   
 
1,081,800
   
Citigroup, Inc.
$
42,796,008
 
560,300
   
JPMorgan Chase & Co.
 
24,636,391
         
$
67,432,399
       
Consumer Finance - 5.2%
   
 
703,000
   
Capital One Financial Corp.
$
40,724,790
 
688,000
   
Discover Financial Services
 
26,522,400
         
$
67,247,190
       
Investment Banking & Brokerage - 1.4%
   
 
139,700
   
The Goldman Sachs Group, Inc.
$
17,820,132
       
Total Diversified Financials
$
152,499,721
       
Insurance - 6.7%
   
       
Property & Casualty Insurance - 6.7%
   
 
361,900
   
ACE, Ltd.
$
28,879,620
 
340,800
   
The Chubb Corp.
 
25,669,056
 
448,000
   
The Travelers Companies, Inc.
 
32,175,360
         
$
86,724,036
       
Total Insurance
$
86,724,036
       
Software & Services - 4.9%
   
       
Systems Software - 4.9%
   
 
1,459,600
   
Microsoft Corp.
$
39,015,108
 
714,500
   
Oracle Corp.
 
23,807,140
         
$
62,822,248
       
Total Software & Services
$
62,822,248
       
Technology Hardware & Equipment - 2.0%
   
       
Communications Equipment - 2.0%
   
 
1,337,600
   
Cisco Systems, Inc.
$
26,283,840
       
Total Technology Hardware & Equipment
$
26,283,840
       
Semiconductors & Semiconductor Equipment - 1.6%
   
       
Semiconductors - 1.6%
   
 
1,005,900
   
Intel Corp.
$
20,751,717
       
Total Semiconductors & Semiconductor Equipment
$
20,751,717
       
Telecommunication Services - 3.3%
   
       
Integrated Telecommunication Services - 2.0%
   
 
389,800
   
AT&T, Inc.
$
13,140,158
 
297,400
   
Verizon Communications, Inc.
 
12,868,498
         
$
26,008,656
       
Wireless Telecommunication Services - 1.3%
   
 
642,500
   
Vodafone Group Plc (A.D.R.)
$
16,184,575
       
Total Telecommunication Services
$
42,193,231
       
TOTAL COMMON STOCKS
   
       
(Cost $1,125,705,469)
$
1,295,014,108
             
       
TOTAL INVESTMENT IN SECURITIES - 99.9%
$
1,295,014,108
       
(Cost $1,125,705,468) (a)
   
       
OTHER ASSETS & LIABILITIES - 0.1%
$
1,856,819
       
TOTAL NET ASSETS - 100.0%
$
1,296,870,927
             
             
             
 
(A.D.R.)
 
American Depositary Receipts.
   
             
 
*
   
Non-income producing security.
   
             
 
(a)
   
At December 31, 2012, the net unrealized gain on investments based on
       
cost for federal income tax purposes of $1,127,333,759 was as follows:
             
       
Aggregate gross unrealized gain for all investments in which
       
there is an excess of value over tax cost
$
178,583,571
             
       
Aggregate gross unrealized loss for all investments in which
       
there is an excess of tax cost over value
 
(10,903,222)
             
       
Net unrealized gain
$
167,680,349
             
             
Various inputs are used in determining the value of the Fund's investments.  These inputs are summarized in the three broad levels listed below.
             
Level 1 – quoted prices in active markets for identical securities
   
Level 2 – other significant observable inputs (including quoted prices for similar securities, interest rates, prepayment speeds, credit risk, etc.)
Level 3 – significant unobservable inputs (including the Fund's own assumptions in determining fair value of investments)
             
Generally, equity securities are categorized as Level 1, fixed income securities and senior loans as Level 2 and securities valued
using fair value methods (other than prices supplied by independent pricing services) are categorized as Level 3.
See Notes to Financial Statements - Note 1A.
   
The following is a summary of the inputs used as of December 31, 2012, in valuing the Fund's assets:



   
Level 1
   
Level 2
   
Level 3
   
Total
 
Common Stocks
  $ 1,295,014,108     $ -     $ -     $ 1,295,014,108  
Total
  $ 1,295,014,108     $ -     $ -     $ 1,295,014,108  

ITEM 2. CONTROLS AND PROCEDURES. (a) Disclose the conclusions of the registrant's principal executive and principal financial officers, or persons performing similar functions, regarding the effectiveness of the registrant's disclosure controls and procedures (as defined in Rule 30a-3(c) under the Act (17 CFR 270.30a-3(c))) as of a date within 90 days of the filing date of the report that includes the disclosure required by this paragraph, based on the evaluation of these controls and procedures required by Rule 30a-3(b) under the Act (17 CFR 270.30a-3(b))) and Rule 13a-15(b) or 15d-15(b) under the Exchange Act (17 CFR 240.13a-15(b) or 240.15d-15(b)). The registrant's principal executive officer and principal financial officer have concluded that the registrant's disclosure controls and procedures are effective based on their evaluation of these controls and procedures as of a date within 90 days of the filing date of this report. (b) Disclose any change in the registrant's internal controls over financial reporting (as defined in Rule 30a-3(d) under the Act (17 CFR 270.30a-3(d)) that occurred during the registrant's last fiscal quarter that has materially affected, or is reasonably likely to materially affect, the registrant's internal control over financial reporting. There were no significant changes in the registrant's internal control over financial reporting that occurred during the second fiscal quarter of the period covered by this report that have materially affected, or are reasonably likely to materially affect, the registrant's internal control over financial reporting. ITEM 3. EXHIBITS. (a) A separate certification for each principal executive officer and principal financial officer of the registrant as required by Rule 30a-2(a) under the Act (17 CFR 270.30a-2(a)). Filed herewith. <PAGE> SIGNATURES [See General Instruction F] Pursuant to the requirements of the Securities Exchange Act of 1934 and the Investment Company Act of 1940, the registrant has duly caused this report to be signed on its behalf by the undersigned, thereunto duly authorized. (Registrant) Pioneer Value Fund By (Signature and Title)* /s/ John F. Cogan, Jr. John F. Cogan, Jr, President Date March 1, 2013 Pursuant to the requirements of the Securities Exchange Act of 1934 and the Investment Company Act of 1940, this report has been signed below by the following persons on behalf of the registrant and in the capacities and on the dates indicated. By (Signature and Title)* /s/ John F. Cogan, Jr. John F. Cogan, Jr., President Date March 1, 2013 By (Signature and Title)* /s/ Mark Bradley Mark Bradley, Treasurer Date March 1, 2013 * Print the name and title of each signing officer under his or her signature.
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