By Tom Fairless 

BRUSSELS--A cache of secret tax documents released Tuesday shed further light on how Luxembourg has helped multinational companies to lower their tax bills, in a second major leak that could intensify pressure on the Grand Duchy to alter its tax practices.

The latest documents, disclosed by the Washington-based International Consortium of Investigative Journalists at late evening local time in Brussels, show how 35 major companies, including Walt Disney Co. and Koch Industries Inc., used complex financial structures to funnel profits through subsidiaries in Luxembourg, potentially avoiding taxes in other jurisdictions.

In a statement Wednesday, Luxembourg's finance ministry said tax avoidance by multinational companies couldn't be blamed on one country alone, and criticized the "highly questionable" way in which the documents were acquired.

"Luxembourg agrees that the legitimacy of certain mechanisms, which are compliant with international and national law, can be put in doubt from an ethical point of view," the ministry said. "The analysis of this situation calls for a broad perspective, and cannot be limited to one country's regulatory framework."

One Disney subsidiary reported a pretax profit in Luxembourg of more than EUR1 billion ($1.2 billion) over four years, but it paid just EUR2.8 million of tax, according to the ICIJ, a tax rate of about 0.25%.

A spokeswoman for Disney called the disclosures "deliberately misleading, " adding that "Disney's global tax rate has averaged 34% over the past five years." She said the Luxembourg arrangement hadn't "meaningfully affected the taxes we pay in any jurisdiction globally."

The ICIJ said the centerpiece of privately held Koch's tax arrangements was an internal bank called Arteva Europe, which managed the cash flows of the conglomerate's European operations through Luxembourg. A Koch subsidiary paid $6.4 million in taxes on $269 million in profits from 2010 through 2013, the group said.

Koch representatives couldn't be reached for comment.

The disclosures come amid a determined push by governments, particularly in Europe, to put an end to financial maneuvers that allow multinational companies to shift profits to tax havens from the higher-tax jurisdictions in which they are earned. But previous efforts to curb tax avoidance and evasion have made painfully slow progress, in part because all European Union governments must sign off on changes to the bloc's tax legislation.

The first set of leaked Luxembourg tax documents, published a month ago, revealed details of deals negotiated by accounting firm PricewaterhouseCoopers for more than 340 of the world's biggest companies, including package-delivery company FedEx Corp. and food-and-beverage giant PepsiCo Inc.

At the time FedEx and PepsiCo defended their practices, saying they did nothing improper.

The latest batch of documents show that the other so-called "Big Four" accounting firms--Ernst & Young, Deloitte and KPMG--negotiated similarly aggressive tax deals in the Grand Duchy.

Other companies that appear this time include Hong Kong-based conglomerate Hutchison Whampoa Ltd.

Ernst & Young and PwC both said their tax advice was in accordance with applicable laws, and that they couldn't comment on individual cases because of client confidentiality. PwC said the reports on its tax advice were "based on partial, incomplete information, which was illegally obtained." Deloitte and KPMG couldn't be reached.

At issue are advance tax agreements, or so-called comfort letters, from Luxembourg authorities that provide certainty to companies about how much tax they must pay. Such deals are legal provided they don't offer special treatment to some companies and not others.

The European Commission, the EU's executive arm, in recent months has opened investigations into tax deals struck by four multinational companies that it says received special treatment-- Apple Inc. in Ireland, Amazon.com Inc. and Fiat SpA in Luxembourg, and Starbucks Corp. in the Netherlands. Those companies have denied receiving special treatment.

The latest leak is likely to put fresh pressure on recently appointed European Commission President Jean-Claude Juncker, who was Luxembourg's prime minister when most of these agreements were struck.

Mr. Juncker survived a no-confidence vote by the European Parliament last month over his involvement in Luxembourg's controversial tax practices after the two main political blocs stood behind him.

"By continuing to do pretty much nothing, European leaders seem content to allow billions in tax revenue to slip through their fingers," said Natalia Alonso, a deputy director of campaigns at the humanitarian group Oxfam, which lobbies against tax avoidance. "Europe cannot wait any longer."

The EU's new competition commissioner, Margrethe Vestager has said she would pursue the tax investigations as a matter of priority. Her role it is to scrutinize tax deals that are deemed to represent government aid that favors some companies over their rivals.

Ms. Vestager said last month that she considered the first batch of Luxembourg documents as "market information" that she could potentially use to launch further probes.

Mr. Juncker, who also served as Luxembourg's finance minister for two decades, has played down his role in overseeing Luxembourg's tax system. "The tax administration doesn't have to report to the finance minister," he said in November.

Write to Tom Fairless at tom.fairless@wsj.com

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